PIPages
Labs

Claudia Avalos

New York University, NY·Chemistry·Early-career

Some molecules have electron and nuclear spins, a tiny magnetic property, that can be controlled with light or other electromagnetic radiation. Such molecules could serve as quantum sensors, devices that use spin states to detect magnetic fields, rotation or temperature at very small scales.

Fields

Chemistry

Physics

Topics

chromophore-radical dyads

nuclear magnetic resonance

hyperpolarization

Grants
1 known grant, through Jun 2029

What they work on

  1. Determine how the structure of chromophore-radical dyads, molecules pairing a light absorber with an unpaired-electron unit, controls the mechanism by which light polarizes the radical's spin, using combined computational and experimental studies.
  2. Identify how dyad structure affects the transfer of spin polarization from the radical to neighboring nuclear spins, which could boost NMR signals.
  3. Establish design rules linking spin-spin coupling, magnetic anisotropy, orbital overlap and spin relaxation to the size and sign of polarization, and the magnetic field and temperature conditions where it can be reached.

More about the research

They could also strengthen the signal in nuclear magnetic resonance (NMR), a widely used method that reads molecular structure from nuclear spins but is limited by weak signals. The question is which molecular structures make spins easy to control with light.

Why it matters

Magnetic resonance methods are widely used in the chemical industry but are limited by weak signals. Molecules that produce strong spin polarization with light could make NMR more sensitive for small samples without cryogens or expensive microwave equipment. The same design principles could guide quantum sensors for gyroscopes, magnetic field detection and nanoscale temperature measurement.

Known grants

From NIH and NSF research grants. Labs often have other funding we can't see.

CAREER: Directed Molecular Design of Chromophore-Radical Dyads for Optical Pumping of Doublet Ground States

NSF · Jul 2024 – Jun 2029

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The school

New York University: 72 labs on PI Pages, $1.5B a year on research, 540 research doctorates a year.

More about New York University

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