PIPages
Labs

Brian Collins

Washington State University, WA·Materials Science

Organic solar cells, made from carbon-based molecules, could be printed cheaply onto flexible surfaces without the toxic lead found in some newer solar materials. They need two kinds of molecules: one that donates electrons and one that accepts them, so that charge can form and move when light hits.

Fields

Materials Science

Physics

Chemistry

Topics

organic photovoltaics

organic solar cells

ternary blends

Grants
1 known grant, through Jul 2027

What they work on

  1. Map the nanoscale arrangement of molecules in three- and four-component organic solar cell blends using spectral analysis of resonant soft X-ray nanoprobes, and correlate structure with device performance.
  2. Analyze charge generation dynamics and energetics under device-relevant conditions to identify the excited-state pathways responsible for the ternary advantage.
  3. Test whether guest molecules collecting at donor-acceptor interfaces lower energy barriers to charge separation, while guests mixed into other domains tune charge transport and non-radiative losses.
  4. Establish the thermodynamic and kinetic limits of these mechanisms to provide a model for optimizing blends through molecular design and device processing.

More about the research

Blends of three or four molecule types have recently pushed efficiencies above 20%. However, why these extra components help, called the "ternary advantage," is not understood, which slows further progress.

Why it matters

Understanding why three- and four-molecule blends perform better could guide the design of printed, lead-free organic solar panels with high efficiency. Such panels could compete in the marketplace as low-cost, flexible renewable energy. The findings could also inform other flexible and biocompatible organic electronic devices.

Known grants

From NIH and NSF research grants. Labs often have other funding we can't see.

Revealing the Nanomorphology and Excited State Dynamics Behind the Ternary Advantage in Organic Photovoltaics

NSF · Aug 2023 – Jul 2027

Closest labs

Francis Spano

Temple University, PA·Chemistry

Develop a Holstein-Peierls Hamiltonian model of molecular H- and J-aggregates that treats excimer formation and emission fully quantum mechanically, alongside absorption and energy transport.

Valentine Vullev

University of California-Riverside, CA·Chemistry

Develop spectroscopic methods using electrochromism (the optical Stark effect, in which local electric fields shift absorption spectra) to probe and map molecular dipoles and the nanometer-scale fields they generate.

Lin Chen

Northwestern University, IL·Chemistry

Track how charge carriers and excitons localize and evolve in organic metal halide hybrids on femtosecond timescales using ultrafast optical spectroscopy.

The school

Washington State University: 22 labs on PI Pages, $403M a year on research, 259 research doctorates a year.

More about Washington State University

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