PIPages
Labs

Kristopher Waynant

University of Idaho, ID·Chemistry

Designing small molecules that grab onto other substances in controlled ways links two practical problems. One is recovering valuable metals from discarded electronics without harsh chemicals.

Fields

Chemistry

Materials Science

Engineering

Topics

e-waste recycling

metal recovery

precious metals

Grants
2 known grants, through Jul 2027

What they work on

  1. Design azothioformamide-based redox-active ligands that oxidatively dissolve zerovalent metals from e-waste, and identify which structural features control dissolution and metal selectivity using combined computation and experiment.
  2. Recover dissolved metals by electrochemical or chemical reduction while regenerating the ligands, toward a circular, sustainable metal recycling process.
  3. Synthesize a library of peptide-based zwitterionic cross-linkers that vary in length, chemistry, charge spacing, charge density and side chains, and build them into polyampholyte hydrogels.
  4. Relate cross-linker structure to hydrogel protein resistance, signaling-molecule delivery, mechanical properties and degradation to define design rules for bioadaptable biomaterials.

More about the research

The other is building water-rich gels the body will accept. Both projects use synthetic organic chemistry to make tailored molecules and then relate their structure to how they perform.

Why it matters

A mild, ligand-based process could let recyclers recover precious and critical metals from e-waste with less harsh chemistry and reusable reagents. Tunable hydrogels that resist protein fouling and deliver biological signals could serve as better biomaterials for treating injury, disease and impairment, with fewer problems of rejection by the body.

Known grants

From NIH and NSF research grants. Labs often have other funding we can't see.

Collaborative Research: CAS-SC: Investigating the Mild Ligand-based Oxidative Dissolution of E-waste Metals and Their Reductive Recovery

NSF · Aug 2024 – Jul 2027

Synthesis of Peptide-based Zwitterionic Cross-linkers and Evaluation in Bioadaptable Hydrogels

NSF · Aug 2023 – Jun 2027

Closest labs

Christopher Graves

Swarthmore College, PA·Chemistry

Synthesize group 13 metal complexes (boron, aluminum, gallium, indium) of tripodal nitroxide ligands, (RTriNOx3–)M, with systematically varied electron-donating and electron-withdrawing substituents.

Paul Chirik

Princeton University, NJ·Chemistry

Discover robust iron and cobalt catalyst precursors in several oxidation states, using oxidatively-induced reductive elimination and arene displacement from metal sandwich compounds.

Xiaobo Chen

University of Missouri-Kansas City, MO·Chemistry

Design and synthesize three series of triazine-crosslinked polyethyleneimine (TCPEI) porous polymers with very different distributions of amine nitrogen types.

The school

University of Idaho: 8 labs on PI Pages, $140M a year on research, 71 research doctorates a year.

More about University of Idaho

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