PIPages
Labs

Mehrdad Negahban

University of Nebraska-Lincoln, NE·Engineering

Plastics like polycarbonate are glasses: rigid, disordered solids that never fully settle into equilibrium. Their stiffness and strength drift over time, depending on how they were heated, cooled and deformed.

Fields

Engineering

Materials Science

Physics

Topics

polymer glasses

glassy polymers

glass transition

Grants
1 known grant, through Mar 2027

What they work on

  1. Extend the Back Stress Expansion model of glassy polymers to include a distribution of relaxation times, the range of timescales over which polymer chains rearrange.
  2. Capture in the model the shift from steep (super-Arrhenius) temperature dependence of relaxation above the glass transition to a weaker dependence in the glassy state.
  3. Generalize the model to a full multi-dimensional framework so it can describe non-isotropic and large, nonlinear deformations of polymer glasses.
  4. Validate the model using new pressure-dependent structural recovery, constant-volume (isochoric) and nonlinear viscoelastic measurements on polycarbonate, polysulfone and PMMA.

More about the research

Engineers cannot reliably predict how such polymer glasses behave after years of service. That gap holds back their use in electronic thin films and in structural composites for aircraft, cars and wind turbines.

Why it matters

Polymer glasses appear in aerospace, automotive and wind turbine composites and in electronic thin films, but their properties shift with age and use, so designers struggle to estimate part lifetimes. A validated predictive model could let engineers design these materials and components with more confidence in their long-term mechanical and thermal behavior.

Known grants

From NIH and NSF research grants. Labs often have other funding we can't see.

Collaborative Research: New Approaches to Predicting Long-time Behavior of Polymer Glasses

NSF · Apr 2024 – Mar 2027

Closest labs

Yuhang Hu

Georgia Institute of Technology, GA·Engineering

Formulate thermodynamically consistent constitutive laws from statistical models of evolving polymer networks, so that growth, degrowth, remodeling and stiffness change emerge from coupled reaction, transport and deformation.

Neda Maghsoodi

University of Southern California, CA·Materials Science

Measure how focused ultrasound produces localized heating, phase transition, deformation, and recovery in programmed liquid crystal elastomers, recording temperature fields, deformation histories, and material properties across ultrasound conditions and material architectures.

You-Yeon Won

Purdue University, IN·Materials Science

Determine how micelle shape controls interfacial mechanics by comparing spherical and cylindrical poly(styrene)-poly(ethylene glycol) micelles spread at the air-water interface, using Langmuir isotherms, X-ray reflectivity, grazing-incidence X-ray scattering, and Brewster angle microscopy.

The school

University of Nebraska-Lincoln: 17 labs on PI Pages, $657M a year on research, 261 research doctorates a year.

More about University of Nebraska-Lincoln

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